1 Wang, S., Hu, Y., Kouznetsova, T. B., Sapir, L., Chen, D., Herzog-Arbeitman, A., Johnson, J. A., Rubinstein, M., & Craig, S. L. (2023). Facile mechano chemical cycloreversion of polymer cross-linkers enhances tear resistance. Science, 380(6651), 1248-1252. https://doi.org/10.1126/science.adg3229. PMid:37347867.

2 Zhang, J., Chang, Y., Jin, S., Yang, H., Chen, S., Zhang, W., & Chen, Y. (2023). Study on the preparation and performance of SiC nanoparticle reinforced polyurethane coatings. Journal of Applied Polymer Science, 140(30), e54096. https://doi.org/10.1002/app.54096.

3 Meng, X., Qiao, Y., Do, C., Bras, W., He, C., Ke, Y., Russell, T. P., & Qiu, D. (2022). Hysteresis-free nanoparticle-reinforced hydrogels. Advanced Materials, 34(7), 2108243. https://doi.org/10.1002/adma.202108243. PMid:34837255.

4 Singh, R. K., Gangwar, S., & Singh, D. K. (2023). Experimental analysis with GRA-PCA-based hybrid optimization to analyze the effect of hydroxyapatite nanoparticle-reinforced UHMWPE for hip joint. Journal of Advanced Manufacturing Systems, 22(02), 423-444. https://doi.org/10.1142/S021968672350021X.

5 Yin, X., Pang, H., Luo, Y., & Zhang, B. (2021). Eco-friendly functional two-component flame-retardant waterborne polyurethane coatings: a review. Polymer Chemistry, 12(38), 5400-5411. https://doi.org/10.1039/D1PY00920F.

6 Wei, Z., Liu, Z., Fu, X., Wang, Y., Yuan, A., & Lei, J. (2021). Effect of crystalline structure on water resistance of waterborne polyurethane. European Polymer Journal, 157(2), 110647. https://doi.org/10.1016/j.eurpolymj.2021.110647.

7 Peng, Z., Tang, L., Yuan, Y., & Qu, J. (2020). Synthesis and properties of water-dispersible polyisocyanates carrying sulfonate. Journal of Coatings Technology and Research, 17(2), 345-359. https://doi.org/10.1007/s11998-019-00277-4.

8 Gong, C., Xiao, B., Hu, X., Xian, Y., Wang, P., Yang, Y., Luo, X., Li, M., Liu, J., Ding, Y., Xu, P., & Liu, C. (2022). A waterborne polyurethane-based hybrid fluorescent silicon quantum dot. Journal of Applied Polymer Science, 139(35), e52824. https://doi.org/10.1002/app.52824.

9 Mumtaz, F., Zuber, M., Zia, K. M., Jamil, T., & Hussain, R. (2013). Synthesis and properties of aqueous polyurethane dispersions: influence of molec-ular weight of polyethylene glycol. Korean Journal of Chemical Engineering, 30(12), 2259-2263. https://doi.org/10.1007/s11814-013-0166-9.

10 Dall Agnol, L., Dias, F. T. G., Ornaghi, H. L., Jr., Sangermano, M., & Bianchi, O. (2021). UV-curable waterborne polyurethane coatings: A state of the art and recent advances review. Progress in Organic Coatings, 154, 106156. https://doi.org/10.1016/j.porgcoat.2021.106156.

11 Xu, X., Zhou, Z., Qin, L., Yu, C., & Zhang, F. (2022). Preparation of PVA/PU/PUA microcapsules and application in self-healing two-component waterborne polyurethane coatings. Journal of Coatings Technology and Research, 19(3), 977-988. https://doi.org/10.1007/s11998-021-00577-8.

12 Guo, L., Huang, S., & Qu, J. (2018). Synthesis and properties of high-func-tionality hydroxyl-terminated polyurethane dispersions. Progress in Organic Coatings, 119, 214-220. https://doi.org/10.1016/j.porgcoat.2018.02.033.

13 Sheng, Y., Wang, M., Zhang, K., Wu, Z., Chen, Y., & Lu, X. (2021). An “inner soft external hard”, scratch-resistant, self-healing waterborne poly(urethane-urea) coating based on gradient metal coordination structure. Chemical Engineering Journal, 426, 131883. https://doi.org/10.1016/j.cej.2021.131883.

14 Xia, P., Liu, P., Wu, S., Zhang, Q., Wang, P., Hu, R., Xing, K., Liu, C., Song, A., Yang, X., & Huang, Y. (2022). Highly stretchable and sensitive flexible resistive strain sensor based on waterborne polyurethane polymer for wearable electronics. Composites Science and Technology, 221, 109355. https://doi.org/10.1016/j.compscitech.2022.109355.

15 Fazeli, M., Liu, X., & Rudd, C. (2022). The effect of waterborne polyurethane coating on the mechanical properties of epoxy-based composite containing recycled carbon fibres. Surfaces and Interfaces, 29, 101684. https://doi.org/10.1016/j.surfin.2021.101684.

16 Malik, M., & Kaur, R. (2018). Influence of aliphatic and aromatic isocyanates on the properties of poly(ether ester) polyol based PU adhesive system. Polymer Engineering and Science, 58(1), 112-117. https://doi.org/10.1002/pen.24537.

17 Li, J., Han, X., Huyan, C., Liu, D., Li, X., Li, H., & Chen, F. (2023). Hindered phenolic antioxidant modified waterborne polyurethane films with excellent thermal stability and anti-aging performance at high temperature. Progress in Organic Coatings, 176, 107398. https://doi.org/10.1016/j.porgcoat.2022.107398.

18 Zhang, H., She, Y., Zheng, X., Chen, H.-Y., & Pu, J.-W. (2014). Optical and mechanical properties of polyurethane/surface-modified nanocrystalline cellulose composites. Chinese Journal of Polymer Science, 32(10), 1363-1372. https://doi.org/10.1007/s10118-014-1526-6.

19 Fu, J., Yu, H., Wang, L., Lin, L., & Khan, R. U. (2020). Preparation and properties of UV-curable hyperbranched polyurethane acrylate hard coatings. Progress in Organic Coatings, 144, 105635. https://doi.org/10.1016/j.porgcoat.2020.105635.

20 Huang, P.-H., Laakso, M., Edinger, P., Hartwig, O., Duesberg, G. S., Lai, L.-L., Mayer, J., Nyman, J., Errando-Herranz, C., Stemme, G., Gylfason, K. B., & Niklaus, F. (2023). Three-dimensional printing of silica glass with sub-micrometer resolution. Nature Communications, 14(1), 3305. https://doi.org/10.1038/s41467-023-38996-3. PMid:37280208.

21 Bauer, J., Crook, C., & Baldacchini, T. (2023). A sinterless, low-temperature route to 3D print nanoscale optical-grade glass. Science, 380(6648), 960-966. https://doi.org/10.1126/science.abq3037. PMid:37262172.

22 Zhang, W., Zhuang, X., Li, X., Lin, Y., Bai, J., & Chen, Y. (2009). Preparation and characterization of organic/inorganic hybrid polymers containing polyhedral oligomeric silsesquioxane via RAFT polymerization. Reactive & Functional Polymers, 69(2), 124-129. https://doi.org/10.1016/j.reactfunctpolym.2008.11.009.

23 Liu, Y., Zeng, K., & Zheng, S. (2007). Organic-inorganic hybrid nanocomposites involving novolac resin and polyhedral oligomeric silsesquioxane. Reactive & Functional Polymers, 67(7), 627-635. https://doi.org/10.1016/j.reactfunctpolym.2007.04.002.

24 Chen, K., Liu, H., Zhou, J., Sun, Y., & Yu, K. (2022). Polyurethane blended with silica-nanoparticle-modified graphene as a flexible and superhydrophobic conductive coating with a self-healing ability for sensing applications. ACS Applied Nano Materials, 5(1), 615-625. https://doi.org/10.1021/acsanm.1c03414. PMid:35128341.

25 Fu, P., Ou, J., He, Y., Hu, Y., Wang, F., Fang, X., Li, W., & Amirfazli, A. (2024). Robust superhydrophobic coating with carbon nanotubes and silica nanoparticles in the matrix of fluorinated polyurethane. Surfaces and Interfaces, 45, 103890. https://doi.org/10.1016/j.surfin.2024.103890.

26 Jie, L., Nan, Z., Zonglin, L., Ze, L., Guoqing, W., Lishuang, G., & Jing, L. (2022). Fast self-healing and antifouling polyurethane/fluorinated polysiloxane-microcapsules-silica composite material. Advanced Composites and Hybrid Materials, 5(3), 1899-1909. https://doi.org/10.1007/s42114-022-00515-1.

27 Yanan, Z., Yeming, S., Minhui, W., & Xun, L. (2022). UV-curable self-healing, high hardness and transparent polyurethane acrylate coating based on dynamic bonds and modified nano-silica. Progress in Organic Coatings, 172, 107051. https://doi.org/10.1016/j.porgcoat.2022.107051.

28 Chen, D., Yi, S., Wu, W., Zhong, Y., Liao, J., Huang, C., & Shi, W. (2010). Synthesis and characterization of novel room temperature vulcanized (RTV) silicone rubbers using Vinyl-POSS derivatives as cross linking agents. Polymer, 51(17), 3867-3878. https://doi.org/10.1016/j.polymer.2010.06.028.

29 Chen, D., Nie, J., Yi, S., Wu, W., Zhong, Y., Liao, J., & Huang, C. (2010). Thermal behaviour and mechanical properties of novel RTV silicone rubbers using divinyl-hexa[(trimethoxysilyl)ethyl]-POSS as cross-linker. Polymer Degradation & Stability, 95(4), 618-626. https://doi.org/10.1016/j.polymdegradstab.2009.12.002.

30 Uragami, T., Tsukamoto, K., Inui, K., & Miyata, T. (1998). Pervaporation characteristics of a benzoyl chitosan membrane for benzene-cyclohexane mixtures. Macromolecular Chemistry and Physics, 199(1), 49-54. https://doi.org/10.1002/(SICI)1521-3935(19980101)199:1<49::AID-MACP49>3.0.CO;2-B.

31 Anand, A., Jirimali, H. D., Kulkarni, R. D., & Gite, V. (2018). Utilisation of sebacic acid and nanohydroxyapatite in polyurethane nanocomposite coating. Green Materials, 6(2), 65-75. https://doi.org/10.1680/jgrma.17.00028.

32 Lin, W., Liu, Z., Li, Q., Rong, Q., Zu, H., & Sang, M. (2020). Dehydration of caprolactam–water mixtures by composite membranes with nano silica/polyacrylate active layer by emulsion polymerization. Desalination and Water Treatment, 208, 125-135. https://doi.org/10.5004/dwt.2020.26464.

33 Qin, L., Chuanwen, L., Dingding, X., & Dongzhi, C. (2021). Separation of green solvent dimethyl carbonate/methanol azeotropic mixture by pervaporation with polydimethylsiloxane/polyhedral oligomeric silsesquioxane composite membrane. Global NEST Journal, 23(3), 458-467. https://doi.org/10.30955/gnj.003512.

34 Kang, J.-M., Cho, H.-J., Lee, J., Lee, J.-I., Lee, S.-K., Cho, N.-S., Hwang, D.-H., & Shim, H.-K. (2006). Highly bright and efficient electroluminescence of new PPV derivatives containing polyhedral oligomeric silsesquioxanes (POSS) and their bends. Macromolecules, 39(15), 4999-5008. https://doi.org/10.1021/ma0603377.

35 Wahab, M. A., Mya, K. Y., & He, C. (2010). Synthesis, morphology, and properties of hydroxyl terminated-POSS/polyimide low-k nanocomposite films. Journal of Polymer Science. Part A, Polymer Chemistry, 46(17), 5887-5896. https://doi.org/10.1002/pola.22906.

36 Zhao, H., She, W., Shi, D., Wu, W., Zhang, Q.-C., & Li, R. K. Y. (2019). Polyurethane/POSS nanocomposites for superior hydrophobicity and high ductility. Composites. Part B, Engineering, 177, 107441. https://doi.org/10.1016/j.compositesb.2019.107441.

37 Wang, X., Chen, G.-X., Han, R., Zhou, Z., & Li, Q. (2024). Controlled synthesis of non-functionalized POSS nanoparticles with hydrophobic to hydrophilic wettability transition. Progress in Organic Coatings, 191, 108398. https://doi.org/10.1016/j.porgcoat.2024.108398.

38 Prządka, D., Marcinkowska, A., & Andrzejewska, E. (2016). POSS-modified UV-curable coatings with improved scratch hardness and hydrophobicity. Progress in Organic Coatings, 100, 165-172. https://doi.org/10.1016/j.porgcoat.2016.01.011.

39 Ghermezcheshme, H., Mohseni, M., & Yahyaei, H. (2015). Use of nanoindentaion and nanoscratch experiments to reveal the mechanical behavior of POSS containing polyurethane nanocomposite coatings: the role of functionality. Tribology International, 88, 66-75. https://doi.org/10.1016/j.triboint.2015.02.023.

40 Adapala, P., Gaur, S., Puri, R. G., & Khanna, A. S. (2015). Development and evaluation of nano-silica dispersed polyurethane based coatings for improved anti-graffiti and scratch resistance. Open Journal of Applied Sciences, 5(12), 808-818. https://doi.org/10.4236/ojapps.2015.512077.

41 Mariateresa, L., & Maurizio, M. (2014). Surface characterization and effectiveness evaluation of anti-graffiti coatings on highly porous stone materials. Applied Surface Science, 288, 466-477. https://doi.org/10.1016/j.apsusc.2013.10.056.

42 Rossi, S., Deflorian, F., & Fedel, M. (2019). Polysilazane-based coatings: corrosion protection and anti-graffiti properties. Surface Engineering, 35(4), 343-350. https://doi.org/10.1080/02670844.2018.1465748.

43 Rabea, A. M., Mirabedini, S. M., & Mohseni, M. (2012). Investigating the surface properties of polyurethane based anti-graffiti coatings against UV exposure. Journal of Applied Polymer Science, 124(4), 3082-3091. https://doi.org/10.1002/app.35344.

44 Rabea, A. M., Mohseni, M., Mirabedini, S. M., & Hashemi Tabatabaei, M. (2012). Surface analysis and anti-graffiti behavior of a weathered polyurethane-based coating embedded with hydrophobic nano silica. Applied Surface Science, 258(10), 4391-4396. https://doi.org/10.1016/j.apsusc.2011.12.123.

45 Amrutkar, S., More, A., Mestry, S., & Mhaske, S. T. (2022). Recent developments in the anti-graffiti coatings: an attentive review. Journal of Coatings Technology and Research, 19(3), 717-739. https://doi.org/10.1007/s11998-021-00580-z.