Polímeros: Ciência e Tecnologia
https://www.revistapolimeros.org.br/article/doi/10.1590/0104-1428.20250061
Polímeros: Ciência e Tecnologia
Original Article

Innovations in sustainable additive manufacturing: PLA, Amazon wood waste, Brazil nut oil

Jackeline Lira Bremgartner; Joaquim dos Santos; Lizandro Manzato; Vitor Bremgartner; Claudete Catanhede do Nascimento

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Abstract

Responding to the growing interest in lignocellulosic materials for 3D printing, this research addresses the need for sustainable solutions, employing Amazonian wood waste and Brazil nut oil (BNO) as a natural binder for polylactic acid (PLA). We successfully developed filaments from a composition of 4% powdered sawdust of Nectandra rubra and Zygia racemosa, respectively with medium and high density, with 91% PLA and 5% BNO, which were extruded and printed. Physical-mechanical and characterization tests were performed using SEM, TGA, and FTIR. The incorporation of wood increased flexural strength, but reduced compression and tensile strength. FTIR analysis showed compatibility between the components, although the addition of wood caused agglomeration as indicated by SEM. The high-density species increased the thermal stability, as indicated by TGA. This study confirms the potential of filament developed with Amazonian woods and BNO, opening new avenues for sustainable additive manufacturing.

 

 

Keywords

3D printing, biocomposite, extrusion, polymers, vegetable oil

References

1 Hidalgo-Carvajal, D., Muñoz, Á. H., Garrido-González, J. J., Carrasco-Gallego, R., & Montero, V. A. (2023). Recycled PLA for 3D printing: a comparison of recycled PLA filaments from waste of different origins after repeated cycles of extrusion. Polymers, 15(17), 3651. https://doi.org/10.3390/polym15173651. PMid:37688276.

2 Khan, M. Z. R., Srivastava, S. K., & Gupta, M. K. (2020). A state-of-the-art review on particulate wood polymer composites: processing, properties and applications. Polymer Testing, 89, 106721. https://doi.org/10.1016/j.polymertesting.2020.106721.

3 Das, A. K., Agar, D. A., Rudolfsson, M., & Larsson, S. H. (2021). A review on wood powders in 3D printing: processes, properties and potential applications. Journal of Materials Research and Technology, 15, 241-255. https://doi.org/10.1016/j.jmrt.2021.07.110.

4 Song, Y., Li, Y., Song, W., Yee, K., Lee, K.-Y., & Tagarielli, V. L. (2017). Measurements of the mechanical response of unidirectional 3D-printed PLA. Materials & Design, 123, 154-164. https://doi.org/10.1016/j.matdes.2017.03.051.

5 Kariz, M., Sernek, M., & Kuzman, M. K. (2016). Use of wood powder and adhesive as a mixture for 3D printing. Holz als Roh- und Werkstoff, 74(1), 123-126. https://doi.org/10.1007/s00107-015-0987-9.

6 Le Duigou, A., Castro, M., Bevan, R., & Martin, N. (2016). 3D printing of wood fibre biocomposites: from mechanical to actuation functionality. Materials & Design, 96, 106-114. https://doi.org/10.1016/j.matdes.2016.02.018.

7 Singh, T., Patnaik, A., Ranakoti, L., Dogossy, G., & Lendvai, L. (2022). Thermal and sliding wear Properties of Wood Waste-Filled Poly(Lactic Acid) Biocomposites. Polymers, 14(11), 2230. https://doi.org/10.3390/polym14112230. PMid:35683903.

8 Huang, Y., Löschke, S., & Proust, G. (2021). In the mix: the effect of wood composition on the 3D printability and mechanical performance of wood-plastic composites. Composites Part C: Open Access, 5, 100140. https://doi.org/10.1016/j.jcomc.2021.100140.

9 Kariz, M., Sernek, M., Obućina, M., & Kuzman, M. K. (2018). Effect of wood content in FDM filament on properties of 3D printed parts. Materials Today. Communications, 14, 135-140. https://doi.org/10.1016/j.mtcomm.2017.12.016.

10 Tao, Y., Wang, H., Li, Z., Li, P., & Shi, S. Q. (2017). Development and application of wood flour-filled polylactic acid composite filament for 3D printing. Materials (Basel), 10(4), 339. https://doi.org/10.3390/ma10040339. PMid:28772694.

11 Pereira, D., Santos, D., Vedoveto, M., Guimarães, J., & Veríssimo, A. (2010). Fatos florestais da Amazônia 2010. Imazon. Retrieved in 2025, July 16, from https://imazon.org.br/publicacoes/fatos-florestais-da-amazonia-2010/

12 Andrade, K. D. C., Santos, A. P. F., Emmert, F., Santos, J., Lima, A. J. N., & Higuchi, N. (2022). Volumetric yield coefficient: the key to regulating virtual credits for Amazon wood. Acta Amazonica, 53(1), 1-8. https://doi.org/10.1590/1809-4392202101602.

13 Nascimento, J. C. (2021). Influência da classificação de toras, características anatômicas e dendrométricas e o tempo de espera entre o corte e o desdobro no rendimento volumétrico da Nectandra rubra (Mez) C. K. Allen (Master’s thesis). Instituto Nacional de Pesquisas da Amazônia, Manaus.

14 Esteves, L. L. (2018). A influência de óleos vegetais sobre a degradação e propriedades do polipropileno reciclado (Master’s thesis). Instituto Politécnico, Universidade do Estado do Rio de Janeiro, Nova Friburgo.

15 Carvalho, A. L. S., Martelli, M. C., Nascimento, S. C. C., & Brasil, D. S. B. (2022). Brazil Nut oil: extraction methods and industrial applications. Research, Social Development, 11(4), e29511427256. https://doi.org/10.33448/rsd-v11i4.27256.

16 Pereira, E., Ferreira, M. C., Sampaio, K. A., Grimaldi, R., Meirelles, A. J. A., & Maximo, G. J. (2019). Physical properties of Amazonian fats and oils and their blends. Food Chemistry, 278, 208-215. https://doi.org/10.1016/j.foodchem.2018.11.016. PMid:30583364.

17 Narlıoğlu, N., Salan, T., & Alma, M. H. (2021). Properties of 3D-printed wood sawdust-reinforced PLA composites. BioResources, 16(3), 5467-5480. https://doi.org/10.15376/biores.16.3.5467-5480.

18 Yang, T.-C., & Yeh, C.-H. (2020). Morphology and mechanical properties of 3d printed wood fiber/polylactic acid composite parts using Fused Deposition Modeling (FDM): the effects of printing speed. Polymers, 12(6), 1334. https://doi.org/10.3390/polym12061334. PMid:32545359.

19 Yang, T.-C. (2018). Effect of extrusion temperature on the physico-mechanical properties of unidirectional Wood Fiber-Reinforced Polylactic Acid Composite (WFRPC) components using fused deposition modeling. Polymers, 10(9), 976. https://doi.org/10.3390/polym10090976. PMid:30960901.

20 Ferreira, G. C., & Hopkins, M. J. G. (2004). Manual de identificação botânica e anatômica. Belém: Embrapa Amazônia Oriental.

21 Sousa, M. H., Magliano, M. M., Camargos, J. A. A., & Souza, M. R. (2002). Madeiras tropicais brasileiras. Brasília: Edições IBAMA.

22 Santana, L., Alves, J. L., Sabino Netto, A. C., & Merlini, C. (2018). Estudo comparativo entre PETG e PLA para Impressão 3D através de caracterização térmica, química e mecânica. Revista Matéria, 23(4), e-12267. https://doi.org/10.1590/S1517-707620180004.0601.

23 Agaliotis, E. M., Ake-Concha, B. D., May-Pat, A., Morales-Arias, J. P., Bernal, C., Valadez-Gonzalez, A., Herrera-Franco, P. J., Proust, G., Koh-Dzul, J. F., Carrillo, J. G., & Flores-Johnson, E. A. (2022). Tensile Behavior of 3D Printed Polylactic Acid (PLA) based composites reinforced with natural fiber. Polymers, 14(19), 3976. https://doi.org/10.3390/polym14193976. PMid:36235924.

24 Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007). Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, 86(12-13), 1781-1788. https://doi.org/10.1016/j.fuel.2006.12.013.

25 Figueroa, M. J. M., & Moraes, P. D. (2009). Comportamento da madeira a temperaturas elevadas. Ambiente Construído, 9(4), 157-174. https://doi.org/10.1590/s1678-86212009000400525.

26 Poletto, M., Zattera, A. J., Forte, M. M. C., & Santana, R. M. C. (2012). Thermal decomposition of wood: influence of wood components and cellulose crystallite size. Bioresource Technology, 109, 148-153. https://doi.org/10.1016/j.biortech.2011.11.122. PMid:22306076.

27 Charis, G., Danha, G., & Muzenda, E. (2020). Characterizations of biomasses for subsequent thermochemical conversion: a comparative study of pine sawdust and acacia tortilis. Processes (Basel, Switzerland), 8(5), 546. https://doi.org/10.3390/pr8050546.

28 Barros, S. S. (2020). Síntese e caracterização de nanocelulose a partir da folha de abacaxi (Ananas comosus (L.) Merr.) (Master’s thesis). Faculdade de Tecnologia, Universidade Federal do Amazonas, Manaus.

29 Siriprom, W., Sangwaranatee, N., Herman, K., Chantarasunthon, K., Teanchai, K., & Chamchoi, N. (2018). Characterization and analyzation of the poly (L-lactic acid) (PLA) films. Materials Today: Proceedings, 5(7), 14803-14806. https://doi.org/10.1016/j.matpr.2018.04.009.

30 Abraham, E., Deepa, B., Pothan, L. A., Jacob, M., Thomas, S., Cvelbar, U., & Anandjiwala, R. (2011). Extraction of nanocellulose fibrils from lignocellulosic fibres: a novel approach. Carbohydrate Polymers, 86(4), 1468-1475. https://doi.org/10.1016/j.carbpol.2011.06.034.

31 Manzato, L., Takeno, M. L., Pessoa-Junior, W. A. G., Mariuba, L. A. M., & Simonsen, J. (2018). Optimization of cellulose extraction from jute fiber by box-behnken design. Fibers and Polymers, 19(2), 289-296. https://doi.org/10.1007/s12221-018-1123-8.

32 Raspolli Galletti, A. M., D’Alessio, A., Licursi, D., Antonetti, C., Valentini, G., Galia, A., & Nassi o Di Nasso, N. (2015). Midinfrared FT-IR as a tool for monitoring herbaceous biomass composition and its conversionto furfural. Journal of Spectroscopy, 2015(1), 719042. https://doi.org/10.1155/2015/719042.

33 Abreu, R., No., Lima, J. T., Takarada, L. M., & Trugilho, P. F. (2021). Efeito do tratamento térmico na morfologia das fibras na pirólise da madeira. Wood Science and Technology, 55(1), 95-108. https://doi.org/10.1007/s00226-020-01238-6.
 

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