Polímeros: Ciência e Tecnologia
https://www.revistapolimeros.org.br/doi/10.1590/0104-1428.2278
Polímeros: Ciência e Tecnologia
Original Article

Mechanical recycling of tags and labels residues using sugarcane bagasse ash

Mantovani, Guilherme Augusto; Oliveira, Jean Halison de; Santos, Andressa dos; Rinaldi, Andrelson Wellington; Moisés, Murilo Pereira; Radovanovic, Eduardo

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Abstract

In this study, an alternative method for recycling residues of labels and stickers (parings) containing biaxically oriented polypropylene (BOPP) and polyurethane-based glue was discussed. The recycling of this type of material is complicated, once the separation and the milling processes are difficult to be accomplished, due to the presence of a large amount of glue. In this study, sugarcane bagasse ash was used to enable the milling process of stickers residues. Composites were prepared with post-consumer polypropylene extrusion with different polypropylene/parings ash ratio. These materials were analyzed by tensile, three point flexural, hardness, density, water absorption, Izod impact tests, thermogravimetric analysis, environmental exposure and scanning electron microscopy. Addition of sticker residues/ash to the polypropylene matrix makes the material more rigid and does not affect significantly thermal and degradation properties. Thus, the recycling process proposed in this paper is environmentally and economically viable.

Keywords

composites, parings, BOPP, recycling, mechanical properties.

References

1. Moisés, M. P., Silva, C. T. P., Meneguin, J. G., Girotto, E. M., & Radovanovic, E. (2013). Synthesis of zeolite NaA from surgarcane bagasse ash. Materials Letters, 108(1), 243-246. http://dx.doi.org/10.1016/j.matlet.2013.06.086.

2. Mano, E. B., Pacheco, E. B. A. V., & Bonelli, C. M. C. (2010). Meio ambiente, poluição e reciclagem. São Paulo: Blucher.

3. Nunes, I. H. S., Vanderlei, R. D., Secchi, M., & Abe, M. A. P. (2008). Estudo das caracteristicas fisicas e químicas da cinza do bagaço de cana-de-açucar para uso na construção. Revista Tecnológica, 17, 39-48. http://dx.doi.org/10.4025/revtecnol.v17i1.

4. Associação Brasileira de Normas Técnicas – ABNT. (2004). ABNT NBR 10004: resíduos sólidos: classificação. Rio de Janeiro: ABNT.

5. Paula, M. O., Tinôco, I. F. F., Rodrigues, C. S., Silva, E. N., & Souza, C. F. (2009). Potencial da cinza do bagaço da cana-de-açúcar como material de substituição parcial de cimento Portland. Revista Brasileira de Engenharia Agrícola e Ambiental, 13(3), 353-357. http://dx.doi.org/10.1590/S1415-43662009000300019.

6. Meier, M. (2014). Sustainable polymers: reduced environmental impact, renewable raw materials and catalysis. Green Chemistry, 16(4), 1672. http://dx.doi.org/10.1039/c4gc90006e.

7. Türkçü, H. N. (2004). Investigation of the crystallinity and orientation of polypropylene with respect to temperature changes using FT-IF, XRD and raman techniques (Master's dissertation). Bilkent University, Ankara.

8. Tartaglione, G., Tabuani, D., Camino, G., & Moisio, M. (2008). PP and PBT composites filled with sepiolite: morphology and thermal behaviour. Composites Science and Technology, 68(2), 451-460. http://dx.doi.org/10.1016/j.compscitech.2007.06.023.

9. Erp, T. B. V., Balzano, L. M., & Peters, G. W. (2012). Oriented gamma phase in isotatic polypropylene homopolymer. ACS Macro Letters, 1(5), 618-622. http://dx.doi.org/10.1021/mz3000978.

10. Canevarolo, S. V. (2003). Técnicas de caracterização de polímeros. São Paulo: Artliber.

11. Sinien, L., Lin, Y., Xiaoguang, Z., & Zongneng, Q. (1992). Microdamage and interfacial adhesion in glass bead-filled high-density polyethylene. Journal of Materials Science, 27(17), 4633-4638. http://dx.doi.org/10.1007/BF01165998.

12. Premalal, H. G. B., Ismail, H., & Baharin, A. (2002). Comparison of the mechanical properties of rice husk powder filled polypropylene composites with talc filled polypropylene composites. Polymer Testing, 21(7), 833-839. http://dx.doi.org/10.1016/S0142-9418(02)00018-1.

13. Demjén, Z., Pukánszky, B., & Nagy, J. (1998). Evaluation of interfacial interaction in polypropylene/surface treated CaCO3 composites. Composites. Part A, Applied Science and Manufacturing, 29(3), 323-329. http://dx.doi.org/10.1016/S1359-835X(97)00032-8.

14. Mareri, P., Bastide, S., Binda, N., & Crespy, A. (1998). Mechanical behaviour of polypropylene composites containing fine mineral filler: Effect of filler surface treatment. Composites Science and Technology, 58(5), 747-752. http://dx.doi.org/10.1016/S0266-3538(97)00156-5.

15. Carvalho, G. M. X., Mansur, H. S., Vasconcelos, W. L., & Oréfice, R. L. (2007). Obtenção de compósitos de resíduos de ardósia e polipropileno. Polímeros: Ciência e Tecnologia, 17(2), 98-103. http://dx.doi.org/10.1590/S0104-14282007000200008.

16. Asuke, F., Aigbodion, V. S., Abdulwahab, M., Fayomi, O. S. I., Popoola, A. P. I., Nwoyi, C. I., & Garba, B. (2012). Effects of bone particle on the properties and microstructure os polypropylene/bone ash particulate composites. Results in Physics, 2(1), 135-141. http://dx.doi.org/10.1016/j.rinp.2012.09.001.

17. Fuad, M. Y. A., Ismail, Z., Ishak, Z. A. M., & Omar, A. K. M. (1995). Application of rice husk ash as fillers in polypropylene: effect of titanate, zirconate and silane coupling agents. European Polymer Journal, 31(9), 885-893. http://dx.doi.org/10.1016/0014-3057(95)00041-0.

18. Ramos, S. M. L. S., Carvalho, L. H., Spieth, E., & Rivadula, R. S. (1993). Efeitos da estabilização do Polipropileno nas propriedades térmicas, mecânicas e termo-mecânicas de compósitos de Polipropileno/Atapulgita. Polímeros: Ciência e Tecnologia, 3(4), 26-31.

19. Thwe, M. M., & Liao, K. (2003). Durability of bamboo-glass fiber reinforced polymer matrix hybrid composites. Composites Science and Technology, 63(3-4), 375-387. http://dx.doi.org/10.1016/S0266-3538(02)00225-7.

20. Rabello, M. S., & White, J. R. (1997). Fotodegradação do polipropileno: um processo essencialmente heterogêneo. Polímeros: Ciência e Tecnologia, 7(2), 47-56.

21. Allen, N. S., Edge, M., Corrales, T., Childs, A., Liauw, C. M., Catalina, F., Peinado, C., Minihan, A., & Aldcroft, D. (1998). Ageing and stabilisation of filled polymers: an overview. Polymer Degradation & Stability, 61(2), 183-199. http://dx.doi.org/10.1016/S0141-3910(97)00114-6.

22. Paoli, M. A. (2009). Degradação e estabilização de polímeros. São Paulo: Artliber.

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